
Potassium tert-Butylate (t-BuOK)

Chemical Formula: C₄H₉OK
1. CAS Number(s)
Potassium tert-butylate: 865-47-4
2. Product Description
Potassium tert-Butylate (t-BuOK) is a strong, non-nucleophilic alkoxide base widely used in organic synthesis and polymer chemistry. Owing to its high basicity and steric hindrance, it enables rapid and selective deprotonation while minimizing side reactions, making it well suited for demanding base-catalyzed processes.
3. Typical Properties (indicative)
Appearance: White to off-white solid (powder or granules)
Assay: ≥ 98%
Solubility: Soluble in polar aprotic solvents; reacts with protic solvents
Reactivity: Very strong base, moisture- and air-sensitive
4. Typical Applications
Strong base for elimination and deprotonation reactions
Anionic polymerization initiation
Synthesis of pharmaceuticals and specialty intermediates
Base-catalyzed rearrangements and condensations
5. Industries Served
Pharmaceuticals & Fine Chemicals
Specialty Chemicals
Polymers & Advanced Materials
6. Packaging
Moisture-tight drums
Inert-gas protected packaging available upon request
7. Storage & Handling
Store under dry, inert conditions. Protect from moisture, air, and heat. Handle using appropriate PPE due to high reactivity.
8. Regulatory & Safety
Strong alkoxide base; corrosive. SDS and CoA available upon request.